Allow removal of "Connected to Windows" accounts from Edge profiles

I too am affected by this issue. I recently added my school (university) account in Edge within a new profile on my work computer and found out that either I get logged in automatically (on some pages) with the wrong account or I have to choose my school account on for each app again. This is really disturbing.
A possibility to unlink accounts from Edge or correctly respect the account used for the profile should really be implemented.

This morning, I logged in within Edge on a Windows Server 2022 while I was trying to setup a backup software. Because that login wasn't kept after clicking on a link with the software, I decided to choose the synchronization option. Now, the account remains linked to the administrator account of that server. I tried every hint I found in this context but failed to remove the connection.
Eventually, I found this discussion. Hopefully, the issue will be corrected soon, although I have little hope considering the request is almost three years old.

I have not played around with profiles in edge, but from experience in Chrome: There will always be one profile profile = where one would be happy to be logged in, but the others are to work faster. They may or may not include a profile login for efficiency reasons.

I have one profile which is my main profile where I am logged into the right things - like f.e. a 365 account, a work account. the other profiles are for different needs and are disconnected from any profile (google) accounts as this is neither needed not wanted.

- one with an empty setup, few bookmarks in the bookmar bar for recording educational videos
- one where specific extensions are loaded. While I am usually logged into chatgpt there is one extension which is useful (Aiprm) but has an obnoxious logo. I have one profile just for that when I quickly want to access that. I have another for extensions I use for research which make the browser slow, so I only start that profile when I need them.
- 2-3 others all signed in for different account types into social networks (I have separate ones for projects, also f.e in german / english) with different settings. Starting these I know I am signed into these accounts and I can work on the project without having to log in or out in these networks.
- one for a publishing workflow - bookmarks and textexpander settings are made for that workflow
- another profile setup for gaming - the bookmarks and bookmark bar are chockfull of all the links I need for that game

The normal user may never use more than one profile. But the people who do usually use it for something similar like I do.

Is there any update to this issue after two years?

I have a daily user account with limited administrative access that I have signed into the computer, and when I go to use Edge for admin work within O365/Azure/EAC, I am constantly having to switch profiles due to Edge being "smart" and noticing that I'm navigating to a Microsoft login page, and "helpfully" signing me in with my Connected to Windows account. This has led to countless redirect loops when attempting to access the Exchange Admin Center, specifically, due to the lack of permissions on my standard, non-admin level account. The loop order is as follows:

1. Bookmark link: https://admin.exchange.microsoft.com/
2. Edge loads page and signs in with non-admin account that is "Connected to Windows"
3. Redirected to https://outlook.office365.com/ecp/ as the EAC portal must notice that the account does not have permissions to sign in
4. Immediate redirected to https://admin.exchange.microsoft.com/?landingpage=homepage&form=ecp_toggle_redirect
5. Redirected back to https://admin.exchange.microsoft.com/
6. Repeat every 2-3 seconds

I don't want to remove the account from the OS via Settings > Accounts > Access Work or School, as this is my company account on my assigned company device. I would prefer to use Edge for this case due to mental compartmentalization and personal work flow, but if this can't be addressed I will simply use Firefox, Brave, or another browser with more granular control.

The profile signed into Edge is the Admin level account, and I've attempted to remove the associated passwords to the portals in question multiple times. From what I can tell, this is caused by Microsoft's Sign In Assistant, and it's all or nothing with no way to opt out of Edge specifically.

Hopefully, Microsoft has been working on and plans to implement a feature of removing, or at least not defaulting & overriding the user-specified default account, the 'Connected To Windows' Microsoft account from the list of sign in options displayed when using Edge browser to navigate to Microsoft Cloud sign in pages, such as the Azure Portal and the Exchange Admin Center. Having it available as a secondary option is nice, but not necessary.

Thank you for your time.

Right on the 2nd bit - but if you accidentally leave the check box - then there is no way out!
I have about 12 different accounts to manage and all it takes is one time to miss that check box - and boom! Now how do I get this account NOT connected to windows! Or how do I change the account? I do have an account I would prefer - but when I tried to leave that manage checkbox on purpose for that account - it gave an error - could not do it! (so presume cannot switch/change either). This is really ugly. There is some way - I managed to do this one time before - same issue - and after enough searching - there is a way to get it out of there - but it's not easy or obvious!
arghhh