Both "Site ID" of servers in server farm, "Application Path" of the application, and "Validation Key", "Decryption Key" of the application should be the same across different servers in server farm.
Site ID is the number assiged by IIS to a site, viewable from IIS -> [Host Name] -> Sites -> the "ID" column on the main pane ("Sites"). e.g. "Default Web Site" always be assigned with ID 1. The site id is editable in the "Advance Setting" of the site.
Application Path is the path name under the site, viewable from IIS -> [Host Name] -> Sites -> [Name of Site, e.g. "Default Web Site"] -> [Application Path, e.g. the name of your application.]
"Validation Key", "Decription Key" viewable from IIS -> [Host Name] -> Sites -> [Name of Site, e.g. "Default Web Site"] -> [Application Path, e.g. the name of your application.] -> Machine Key icon on the main pane. Need to generate in one of the server, and paste to other servers.