Well, I just fixed it. I came across some other forums. While I thought it definitely had to do with the second NIC being installed, the issue ended up being the virus software solution (AVG 2011 in this case) that was causing the problem. I would have never thought this in a million years, as we installed AVG 2011 a couple months ago and we have had access to the EMC just fine. In fact, we had access to EMC moments before we installed the secondary NIC card and powered the server down to install it, as we were in there creating a new user account. However, uninstalling AVG and rebooting the server seemed to fix the WinRM issues which seemed to be causing the EMC issues. What a pain, as I have spent nearly all day chasing my tail. I kept coming across the virus software as a possible issue all day, but never thought to try uninstalling it since it had been working just fine. Lesson learned. Hopefully this feedback might assist others with these problems.