There are shortcuts that make working with the paths in question much quicker.
1. Shift + Right-Click > Copy As Path allows you to grab the full path of a file or folder
2. Enable Quick Edit Mode in Exchange Management Shell: Righ-Click the EMS Window Icon and go to Properties; Check Quick Edit Mode
2a. This allows you to Mark, Copy, and Paste without using the context menu
2b. Left-Click and Drag to Mark, Right-Click with a selection Marked to Copy, Right-Click with no selection to Paste
Get the Full Path of a Folder or File in Windows 7 [Works in other versions]
http://technet.microsoft.com/en-us/magazine/ff678296.aspx
HOW TO: Enable and Disable QuickEdit Mode for MS-DOS Programs in Windows 2000 [This functionality is the same for both Command Prompt and PowerShell]
http://support.microsoft.com/kb/317591/en-us