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"x-up-devcap-post-charset" can be used to trick the current IIS URL Rewrite rule as shown in https://twitter.com/wdormann/status/1582083758047760384/photo/3 mentioned in the comment of CVO123
Nino_Bilic of Microsoft stated: "We are aware of this, yes. We evaluate all such claims, put them though a set of tests and address, if needed."
Despite that Nino_Bilic later asked if "x-up-devcap-post-charset" is related to the Exchange vulnerabilities. A week has passed since these bypasses have been published and neither the Mitigations (https://web.archive.org/web/*/https://officeclient.microsoft.com/getexchangemitigations) nor the documentation regarding "x-up-devcap-post-charset" and "DisableRequestSmuggling" have been improved.
Instead, because Microsoft doesn't seem to offer a SSO federation, we are urged to Create a GitHub Account to get this fixed by ourselves:
https://github.com/MicrosoftDocs/SupportArticles-docs/blob/main/support/developer/webapps/iis/iisadmin-service-inetinfo/httpsys-registry-windows.md
https://referencesource.microsoft.com/#System/net/System/Net/HttpListenerRequest.cs contains "x-up-devcap-post-charset" but the feedback button leads to mailto:refsrcfeedback @ microsoft.com not to a GitHub repo.