PeterForster You can make an "OnPremises" connector and change the configuration for how it identifies the traffic.
New-InboundConnector `
-CloudServicesMailEnabled $true`
-ConnectorType OnPremises`
-Enabled $true`
-Name "Inbound from Postfix On-Premises"`
-RequireTls $true`
-RestrictDomainsToCertificate $true`
-SenderDomains *.domain.com`
-TlsSenderCertificateName *.domain.com`
-TreatMessagesAsInternal $true
Something like that should do the trick. It requires setting the certificate and restricting only traffic with the matching certificate and setting it for OnPremises and as CloudServicesMailEnabled.
I haven't run it in a while, but it worked the last time I checked it.
Back before cross-tenant migrations were possible, I used this same sort of thing to rewrite email addresses by sending traffic to Postfix, letting it rewrite, and then send it along to the appropriate tenant.