There should be profile picker screen feature available in the Edge browser, the feature that already landed in Chrome in Canary.
Whenever you launch Edge browser, it should appear first and give users the option to select which profile you want to launch.
The feature will make it easier for the users do differentiate between Personal and Professional profile. Check the following screenshot:
@vineydhiman Thanks for suggesting this. Feel free to submit this feedback through the browser (Shift+Alt+I) so that our team can keep it together with the other feedback for Multiple Profiles. :)
Fawkes (they/them)Project & Community Manager - Microsoft Edge