The default shortcut has this as a Target:
"C:\Program Files (x86)\Microsoft\Edge Dev\Application\msedge.exe" --profile-directory="Default"
I think if I substitute other values for the profile-directory I can get the shortcut to use a different profile, but am not sure what to name it. I searched around the application and AppData directories but nothing leapt out at me.
@USMA56795The way profile works are the original will be "default". Any additional profiles will start with profile (then a number) like Profile 1, Profile 2, etc. If you want to open your second profile, it will be this below in the Target text box.
"C:\Program Files (x86)\Microsoft\Edge Dev\Application\msedge.exe" --profile-directory="Profile 1"
I hope this helps.